Hi Brian,
There's currently a way for an Admin to modify the Experience your Users have when using either the Android or iOS Mobile Apps for Confluence.
At this time, when a User logs in, they are taken to the "Your Work" view; similar to the Recently Worked on View through the Web.
If you can provide me with a bit more information for what you're looking to see as a "Welcome Page," I can create a Feature Request on your behalf with our Mobile Developers.
-Shawn
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