Hey @NA ,
I think you're best bet here is to use Automation. You can find that under Project Settings -> Automation
Here you can create a rule that runs on either Issue Created or Issue Updated. (depending when you want to set the approver).
Within the automation rule you have the ability to do a field value comparison and then an action. So technically you could say
if custom field = something
then edit issue: set field approvers to this static value
it will be a hardcoded thing so hopefully you don't have 100 different options to go through?
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